Calcium borate

Calcium borate (Ca3(BO3)2), also called Gerstley[1] borate, is a bluish white crystal with a very defined structure. It can be prepared by reacting calcium metal with boric acid. The resulting precipitate is calcium borate. A hydrated form occurs naturally as the minerals colemanite, nobleite and priceite.

Calcium borate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.131
UNII
  • InChI=1S/2BO3.3Ca/c2*2-1(3)4;;;/q2*-3;3*+2 checkY
    Key: VLCLHFYFMCKBRP-UHFFFAOYSA-N checkY
  • InChI=1/4BO3.6Ca/c4*2-1(3)4;;;;;;/q4*-3;6*+2
    Key: KKKYJLNWARAYSD-UHFFFAOYAA
  • InChI=1/2BO3.3Ca/c2*2-1(3)4;;;/q2*-3;3*+2
    Key: VLCLHFYFMCKBRP-UHFFFAOYAG
  • [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-]
  • [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-]
Properties
Ca3(BO3)2
Molar mass 237.852 g/mol
Appearance bluish white crystal
Hazards
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
590 mg/kg (oral, mouse)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

One of its uses is as a binder in some grades of hexagonal boron nitride for hot pressing. Other uses are e.g. flame retardant in epoxy molding compounds, a ceramic flux in some ceramic glazes, reactive self-sealing binders in hazardous waste management,[2] additive for insect-resistant polystyrene,[3] fertilizer, and production of boron glasses.

Also it used as a main source of boron oxide in the manufacturing of ceramic frits that used in the ceramic glaze or ceramic engobe for wall and floor ceramic tiles.

References

  1. For James Gerstley (according to Glazy.org, Gerstley Borate) after whom Gerstley, California is also named
  2. Calcium borate binders. (PDF) . Retrieved on 2010-02-08.
  3. Calcium borate infused foam building materials and the like and method of making same - US Patent 6667350 Claims Archived 2011-06-12 at the Wayback Machine. Patentstorm.us. Retrieved on 2010-02-08.


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