Cerium(IV) perchlorate

Cerium(IV) perchlorate is an inorganic compound composed of cerium and perchloric acid. It has the chemical formula of Ce(ClO4)4.

Cerium(IV) perchlorate
Cerium ion 4 Perchlorate ion.svg
Names
IUPAC name
Cerium(IV) perchlorate
Other names
  • Cerium perchlorate
  • Cerium(4+) perchlorate
  • Cerium tetraperchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.794
EC Number
  • 238-290-8
  • InChI=1S/Ce.4ClHO4/c;4*2-1(3,4)5/h;4*(H,2,3,4,5)/q+4;;;;/p-4
    Key: VDNBDUGCNUZGGR-UHFFFAOYSA-J
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Ce+4]
Properties
Ce(ClO4)4
Molar mass 537.92 g/mol
Density 1.556 g/cm−3 (25 °C)[1]
Melting point 725 °C (1,337 °F; 998 K)
Hazards
GHS labelling:[2]
GHS03: Oxidizing
Warning
H272
P210, P220, P280, P370+P378, P501
Related compounds
Other cations
 Titanium perchlorate, Zirconium perchlorate
Related compounds
 Cerium(III) perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Uses

Cerium(IV) perchlorate is used as a catalyst in organic chemistry for the determination of strontium and for cerimetry.[3][4][5][6] It has a very high redox potential at Ce4+/Ce3+ of +1.87 V in 8 M HClO4.[7]

References
  1. Sigma-Aldrich Co., product no. {{{id}}}.
  2. "Cerium(4+) perchlorate". pubchem.ncbi.nlm.nih.gov.
  3. Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode (2016), Essential Reagents for Organic Synthesis (in German), John Wiley & Sons, p. 80, ISBN 978-1-119-27983-9{{citation}}: CS1 maint: multiple names: authors list (link)
  4. W.J. Mijs, C.R.H.I. de Jonge (2013), Organic Syntheses by Oxidation with Metal Compounds (in German), Springer Science & Business Media, p. 601, ISBN 978-1-4613-2109-5
  5. E. Gagliardi, E. Wolf: Bestimmung von Strontium mit Cer(IV)-perchlorat. In: Microchimica Acta. 51, 1963, S. 578, doi:10.1007/BF01217587.
  6. P. H. List, L. Hörhammer (2013), Allgemeiner Teil. Wirkstoffgruppen I (in German), Springer-Verlag, p. 301, ISBN 978-3-642-47985-4
  7. K.A. Gschneidner, Jr., J.-C.G. Bünzli and V.K. Pecharsky (2006), Handbook on the Physics and Chemistry of Rare Earths (in German), Elsevier, p. 306, ISBN 978-0-08-046672-9{{citation}}: CS1 maint: multiple names: authors list (link)
Compounds containing perchlorate group
HClO4 He
LiClO4 Be(ClO4)2 B(ClO4)−4
B(ClO4)3		 ROClO3 N(ClO4)3
NH4ClO4
NOClO4		 H3OClO4 FClO4 Ne
NaClO4 Mg(ClO4)2 Al(ClO4)3
Al(ClO4)−4
Al(ClO4)2−5
Al(ClO4)3−6		 Si P S ClO−4
ClOClO3
Cl2O7		 Ar
KClO4 Ca(ClO4)2 Sc(ClO4)3 Ti(ClO4)4 VO(ClO4)3
VO2(ClO4)		 Cr(ClO4)3 Mn(ClO4)2 Fe(ClO4)2
Fe(ClO4)3		 Co(ClO4)2,
Co(ClO4)3		 Ni(ClO4)2 Cu(ClO4)2 Zn(ClO4)2 Ga(ClO4)3 Ge As Se Br Kr
RbClO4 Sr(ClO4)2 Y(ClO4)3 Zr(ClO4)4 Nb(ClO4)5 Mo Tc Ru Rh(ClO4)3 Pd(ClO4)2 AgClO4 Cd(ClO4)2 In(ClO4)3 Sn(ClO4)4 Sb TeO(ClO4)2 I Xe
CsClO4 Ba(ClO4)2   Lu(ClO4)3 Hf(ClO4)4 Ta(ClO4)5
TaO(ClO4)3
TaO2ClO4		 W Re Os Ir Pt Au Hg2(ClO4)2,
Hg(ClO4)2		 Tl(ClO4),
Tl(ClO4)3		 Pb(ClO4)2 Bi(ClO4)3 Po At Rn
FrClO4 Ra   Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce(ClO4)x Pr(ClO4)3 Nd(ClO4)3 Pm Sm(ClO4)3 Eu(ClO4)3 Gd(ClO4)3 Tb(ClO4)3 Dy(ClO4)3 Ho(ClO4)3 Er(ClO4)3 Tm(ClO4)3 Yb(ClO4)3
Ac Th(ClO4)4 Pa UO2(ClO4)2 Np Pu Am Cm Bk Cf Es Fm Md No


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