Neodymium nitrate

Neodymium nitrate is a chemical compound with the formula Nd(NO3)3. It is typically encountered as the hexahydrate, Nd(NO3)3·6H2O, which is more accurately formulated as [Nd(NO3)3(H2O)4].2H2O to reflect the crystal structure.[1] It decomposes to NdONO3 at elevated temperature.[2] This water-soluble salt finds use in fabrication of perovskite (CaTiO3) based solid oxide fuel cells, synthesis of Nd3+ doped vanadium pentoxide (V2O5) nanostructure for potential usage in supercapacitors and as a catalyst for Friedlander synthesis of surface modified quinolones for application in medicinal chemistry.[3]

Neodymium(III) nitrate
Names
Other names
Neodymium trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.127
EC Number
  • 233-153-9
  • hexahydrate: InChI=1S/3NO3.Nd.6H2O/c3*2-1(3)4;;;;;;;/h;;;;6*1H2/q3*-1;+3;;;;;;
    Key: VQVDTKCSDUNYBO-UHFFFAOYSA-N
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Nd+3]
  • hexahydrate: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Nd+3]
Properties
Nd(NO3)3
Molar mass 330.25 g/mol (anhydrous)
438.35 g/mol (hexahydrate)
Appearance vibrant pink/violet solid
Density 6.5g/cm3
Melting point 1,374 °C (2,505 °F; 1,647 K)
Structure
Tricapped trigonal prismatic
(nine-coordinate)
Hazards
GHS labelling:
GHS03: OxidizingGHS07: Exclamation mark
Warning
H272, H302, H312, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. Rogers, D. J.; Taylor, N. J.; Toogood, G. E. (1983). "Tetraaquatrinitratoneodymium(III) dihydrate, [Nd(NO3)3(H2O)4].2H2O". Acta Crystallogr. C. 39 (8): 939–941. doi:10.1107/S0108270183006927.
  2. Van Vuuren, C.P.J.; Strydom, C.A. (1986). "The thermal decomposition of neodymium nitrate". Thermochimica Acta. 104: 293–298. doi:10.1016/0040-6031(86)85204-2. ISSN 0040-6031.
  3. Varala, Ravi; Enugala, Ramu; Adapa, Srinivas R. (2006). "Efficient and Rapid Friedlander Synthesis of Functionalized Quinolines Catalyzed by Neodymium(III) Nitrate Hexahydrate". Synthesis. 2006 (22): 3825–3830. doi:10.1055/s-2006-950296.
HNO3 He
LiNO3 Be(NO3)2 B(NO3)4 RONO2 NO3
NH4NO3
HOONO2 FNO3 Ne
NaNO3 Mg(NO3)2 Al(NO3)3
Al(NO3)4
Si P S ClONO2 Ar
KNO3 Ca(NO3)2 Sc(NO3)3 Ti(NO3)4 VO(NO3)3 Cr(NO3)3 Mn(NO3)2 Fe(NO3)2
Fe(NO3)3
Co(NO3)2
Co(NO3)3
Ni(NO3)2 CuNO3
Cu(NO3)2
Zn(NO3)2 Ga(NO3)3 Ge As Se BrNO3 Kr
RbNO3 Sr(NO3)2 Y(NO3)3 Zr(NO3)4 NbO(NO3)3 MoO2(NO3)2 Tc Ru(NO3)3 Rh(NO3)3 Pd(NO3)2
Pd(NO3)4
AgNO3
Ag(NO3)2
Cd(NO3)2 In(NO3)3 Sn(NO3)4 Sb(NO3)3 Te INO3 Xe(NO3)2
CsNO3 Ba(NO3)2   Lu(NO3)3 Hf(NO3)4 TaO(NO3)3 W Re Os Ir Pt(NO3)2
Pt(NO3)4
Au(NO3)3 Hg2(NO3)2
Hg(NO3)2
TlNO3
Tl(NO3)3
Pb(NO3)2 Bi(NO3)3
BiO(NO3)
Po(NO3)4 At Rn
FrNO3 Ra(NO3)2   Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
La(NO3)3 Ce(NO3)3
Ce(NO3)4
Pr(NO3)3 Nd(NO3)3 Pm(NO3)3 Sm(NO3)3 Eu(NO3)3 Gd(NO3)3 Tb(NO3)3 Dy(NO3)3 Ho(NO3)3 Er(NO3)3 Tm(NO3)3 Yb(NO3)3
Ac(NO3)3 Th(NO3)4 PaO2(NO3)3 UO2(NO3)2 Np(NO3)4 Pu(NO3)4 Am(NO3)3 Cm(NO3)3 Bk(NO3)3 Cf Es Fm Md No


This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.