Zirconium(IV) acetate

Zirconium acetate is the acetate of zirconium with the chemical formula Zr(CH3COO)4, or Zr(OAc)4 for short. Zirconium acetate is commercially available in the form of an aqueous solution.

Zirconium(IV) acetate
Names
Other names
Zirconium tetraacetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.021.982
EC Number
  • 224-179-1
  • InChI=1S/4C2H4O2.Zr/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;;;;+4/p-4
    Key: MFFVROSEPLMJAP-UHFFFAOYSA-J
  • CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Zr+4]
Properties
Zr(CH3COO)4
Molar mass 327.408 (anhydrous)
soluble
Related compounds
Related compounds
 zirconium dioxide, zirconium(IV) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Preparation and reactions

Zirconium tetrachloride and acetic acid are heated and reacted in carbon tetrachloride to obtain zirconium(IV) acetate.[1]

It reacts with fluorosulfonic acid to form Zr(CH3COO)n(SO3F)4−n (n=2,3).[2]

References
  1. Pavlov, V. L.; Lysenko, Yu. A.; Kalinichenko, A. A. Synthesis and properties of zirconium tetraacetate.(in Russian) Zhurnal Neorganicheskoi Khimii, 1972. 17(12). ISSN 0044-457X
  2. Sukhjinder Singh; Maninder Bedi; Rajander D. Verma (March 1982). "Zirconium(IV) fluorosulphates: Preparation and characterization". Journal of Fluorine Chemistry. 20 (1): 107–119. doi:10.1016/S0022-1139(00)84023-3.
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